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What are Covalent Organic Frameworks (COFs)?

Covalent organic frameworks

Covalent organic frameworks (COF’s) are a class of extended crystalline organic materials that possess unique properties with high surface areas and adjustable pore sizes. Since the first discovery of the topological frameworks in 2005, COFs have been applied as promising materials in diverse areas such as separation and purification, sensing or catalysis.
Since COF’s are based on carbon and hydrogen they have potential to be a more stable and sustainable class of materials replacing MOF’s that consist of a metal and ligands. MOF’s are widely used in applications like adsorption, membrane separation, sensing, catalysis, and proton conduction.

Making organic frameworks in the form of films is challenging and Carpona is striving to meet this challenge and facilitate research.

References

Ratsch, Ye, Yang, Zhang, Evans and Börjesson

All Carbon-Linked Continuous 3D Porous Aromatic Framework Films with Nanometer Precise Controllable Thickness

Journal of the American Chemical Society2020, 142, 14, 6548–6553.

 

Yang, Mallick, Izquierdo-Ruiz, Schäfer, Xing, Rahm and Börjesson

A Highly Conductive All-Carbon Linked 3D Covalent Organic Framework Film

Small, 2021, 17, 2103152.

 

Yang, Schäfer and Börjesson

Detachable All-Carbon linked 3D Covalent Organic Framework Films for Semiconductor/COF Heterojunctions by Continuous Flow Synthesis

Chem, 2022, DOI:10.1016/j.chempr.2022.05.003